Issue 51, 2012
From the journal:

Chemical Communications

Desymmetrization of cyclohexadienones viad-camphor-derived triazolium salt catalyzed intramolecular Stetter reaction†

Min-Qiang Jiaa  and  Shu-Li You*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, P. R. China
E-mail: slyou@sioc.ac.cn
Fax: (+86) 21-54925087

Abstract

Enantioselective desymmetrization of cyclohexadienones via a D-camphor-derived triazolium salt catalyzed intramolecular Stetter reaction was realized. With 10 mol% of camphor-derived triazolium salt E and 10 mol% of DIEA, various substituted cyclohexadienones proceeded through an intramolecular Stetter reaction, affording tricyclic products in moderate to good yields and excellent ee.

Graphical abstract: Desymmetrization of cyclohexadienones viad-camphor-derived triazolium salt catalyzed intramolecular Stetter reaction

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Article information

DOI
https://doi.org/10.1039/C2CC32783J
Article type
Communication
Submitted
19 Apr 2012
Accepted
08 May 2012
First published
10 May 2012

Chem. Commun., 2012,48, 6363-6365

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Desymmetrization of cyclohexadienones viaD-camphor-derived triazolium salt catalyzed intramolecular Stetter reaction

M. Jia and S. You, Chem. Commun., 2012, 48, 6363 DOI: 10.1039/C2CC32783J

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