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Issue 57, 2012
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One-step conversion of methoxysilanes to aminosilanes: a convenient synthetic strategy to N,O-functionalised organosilanes

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Abstract

A straightforward substitution of silicon-bonded methoxy groups by a lithium amide leading to aminomethoxysilanes is presented. DFT calculations allow thermodynamic insight into the unusual equilibrium conditions. The applicability of N,O-functionalised organosilanes is exemplified by the convenient synthesis of an unsymmetrical methoxydisiloxane.

Graphical abstract: One-step conversion of methoxysilanes to aminosilanes: a convenient synthetic strategy to N,O-functionalised organosilanes

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Article information


Submitted
17 Apr 2012
Accepted
25 May 2012
First published
25 May 2012

Chem. Commun., 2012,48, 7212-7214
Article type
Communication

One-step conversion of methoxysilanes to aminosilanes: a convenient synthetic strategy to N,O-functionalised organosilanes

J. O. Bauer and C. Strohmann, Chem. Commun., 2012, 48, 7212 DOI: 10.1039/C2CC32727A

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