Issue 57, 2012
From the journal:

Chemical Communications

Molecular cable-like 1-D iodic spiral chains covered with triple helices stabilized in guest-included chiral porous framework†

Makoto Tadokoro,*a   Yasuko Tanaka,a   Khoichiro Noguchi,a   Tomoaki Sugayaa  and  Kyosuke Isodaa  

* Corresponding authors

a Tokyo University of Science, Faculty of Science, Department of Chemistry, Kagurazaka 1-3, Tokyo 162-8601, Shinjuku-ku, Japan
E-mail: tadokoro@rs.kagu.tus.ac.jp
Fax: +81-3-5261-4631
Tel: +81-3-5228-0714

Abstract

The supramolecular crystal {[Pr(DMFA)]3[NiII(Hbim)3]2I}n with intricate chiral networks of [NiII(Hbim)3]− molecules is reported. It includes a cationic architecture as a guest, constructed from chiral nanotubes that penetrate I− chains with spiral channels wrapped by triple helices. The I− chains have AC conductivity in crystals like a molecular cable.

Graphical abstract: Molecular cable-like 1-D iodic spiral chains covered with triple helices stabilized in guest-included chiral porous framework

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Article information

DOI
https://doi.org/10.1039/C2CC32289G
Article type
Communication
Submitted
30 Mar 2012
Accepted
15 May 2012
First published
16 May 2012

Chem. Commun., 2012,48, 7155-7157

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Molecular cable-like 1-D iodic spiral chains covered with triple helices stabilized in guest-included chiral porous framework

M. Tadokoro, Y. Tanaka, K. Noguchi, T. Sugaya and K. Isoda, Chem. Commun., 2012, 48, 7155 DOI: 10.1039/C2CC32289G

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