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Issue 19, 2012
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Diastereoselective indium-mediated allylation of N-tert-butanesulfinyl ketimines: easy access to asymmetric quaternary stereocenters bearing nitrogen atoms

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Abstract

Indium-mediated allylation of N-tert-butanesulfinyl ketimines afforded in high yields and diastereoselectivities homoallylic amine derivatives with the nitrogen atom bonded to a quaternary stereocenter.

Graphical abstract: Diastereoselective indium-mediated allylation of N-tert-butanesulfinyl ketimines: easy access to asymmetric quaternary stereocenters bearing nitrogen atoms

  • This article is part of the themed collection: Chirality
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Publication details

The article was received on 30 Nov 2011, accepted on 11 Jan 2012 and first published on 12 Jan 2012


Article type: Communication
DOI: 10.1039/C2CC17493F
Citation: Chem. Commun., 2012,48, 2543-2545
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    Diastereoselective indium-mediated allylation of N-tert-butanesulfinyl ketimines: easy access to asymmetric quaternary stereocenters bearing nitrogen atoms

    J. A. Sirvent, F. Foubelo and M. Yus, Chem. Commun., 2012, 48, 2543
    DOI: 10.1039/C2CC17493F

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