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Abstract | Cited by

The synthesis of MII2 complexes (MII[double bond, length as m-dash]Co, Mn) with terminal hydroxo ligands has been achieved utilizing a dinucleating ligand containing a bridging pyrazolate unit and appended (neopentyl)aminopyridyl groups. Structural studies on the complexes revealed that the MII–OH units are positioned in a syn-configuration, placing the hydroxo ligands in close proximity (ca. 3 Å apart), which may be a prerequisite for water oxidation.

Graphical abstract: Preparation and structures of dinuclear complexes containing MII–OH centers

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