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Issue 88, 2012
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High energy resolution off-resonant spectroscopy at sub-second time resolution: (Pt(acac)2) decomposition

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Abstract

We report on the decomposition of platinum acetylacetonate (Pt(acac)2) in hydrogen induced by flash heating. The changes in the local Pt structure were followed by high energy resolution off-resonant spectroscopy uniquely performed with sub-second time resolution. The decomposition consists of a two-step reduction process of the Pt(II) species.

Graphical abstract: High energy resolution off-resonant spectroscopy at sub-second time resolution: (Pt(acac)2) decomposition

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Article information


Submitted
16 Jul 2012
Accepted
17 Sep 2012
First published
18 Sep 2012

Chem. Commun., 2012,48, 10898-10900
Article type
Communication

High energy resolution off-resonant spectroscopy at sub-second time resolution: (Pt(acac)2) decomposition

J. Szlachetko, M. Nachtegaal, J. Sá, J. Dousse, J. Hoszowska, E. Kleymenov, M. Janousch, O. V. Safonova, C. König and J. A. van Bokhoven, Chem. Commun., 2012, 48, 10898
DOI: 10.1039/C2CC35086F

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