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Issue 11, 2012
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Rhodium catalyzed C–H olefination of N-benzoylsulfonamides with internal alkenes

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Abstract

An annulation via tandem rhodium catalyzed C–H olefination of N-benzoylsulfonamides with internal olefins followed by C–N bond formation is disclosed. A N-substituted quaternary center is formed during the reaction thus providing efficient access to a series of 3,3-disubstituted isoindolinones.

Graphical abstract: Rhodium catalyzed C–H olefination of N-benzoylsulfonamides with internal alkenes

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Supplementary files

Article information


Submitted
09 Nov 2011
Accepted
26 Nov 2011
First published
01 Dec 2011

Chem. Commun., 2012,48, 1674-1676
Article type
Communication

Rhodium catalyzed C–H olefination of N-benzoylsulfonamides with internal alkenes

C. Zhu and J. R. Falck, Chem. Commun., 2012, 48, 1674 DOI: 10.1039/C2CC16963K

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