Issue 11, 2012

Reductive heterocoupling mediated by Cp*2U(2,2′-bpy)

Abstract

Trivalent Cp*2U(2,2′-bpy) (2) (Cp* = C5Me5, 2,2′-bpy = 2,2′-bipyridine), which has a monoanionic bipyridine, was treated with p-tolualdehyde (a), furfuraldehyde (b), acetone (c), and benzophenone (d). Reduction of the C[double bond, length as m-dash]O bond followed by radical coupling with bipyridine forms the U(IV) derivatives [Cp*2U(2,2′-bpy)(OCRR′)] (3a–d).

Graphical abstract: Reductive heterocoupling mediated by Cp*2U(2,2′-bpy)

Supplementary files

Article information

Article type
Communication
Submitted
05 Oct 2011
Accepted
23 Nov 2011
First published
25 Nov 2011

Chem. Commun., 2012,48, 1671-1673

Reductive heterocoupling mediated by Cp*2U(2,2′-bpy)

A. Mohammad, D. P. Cladis, W. P. Forrest, P. E. Fanwick and S. C. Bart, Chem. Commun., 2012, 48, 1671 DOI: 10.1039/C2CC16200H

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