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Abstract | Cited by

Palladium-catalyzed C–H acetoxylation reactions of 2-methoxyimino-2-aryl-acetates and acetamides have been developed. These transformations feature excellent regioselectivity, wide substrate scope, and moderate to good yields. The product can be easily converted into naturally unprecedented α-amino acids in excellent yields.

Graphical abstract: Palladium-catalyzed C–H acetoxylation of 2-methoxyimino-2-aryl-acetates and acetamides

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