Issue 6, 2011
From the journal:

CrystEngComm

An organic–inorganic hybrid heterobridging luminescent copper(i) polymer exhibiting thermochromic behavior†

Hao-Hong Li,a   Yun-Jie Wang,a   Hai-Jun Dong,a   Zhi-Rong Chen,*a   Yan-Ling Wu,a   Min Wanga  and  Shu-Wei Huanga  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, China
E-mail: zrchen@fzu.edu.cn

Abstract

A 3-D organic–inorganic hybrid heterobridging copper(I) polymer {[Cu2I2(Hgtsc)]·2DMF}n (1A) (Hgtsc=glyoxal-dithiosemicarbazone) with an unusual bridging mode involving iodine and sulfur atoms has been structurally determined, which was constructed from supramolecular interactions between 2-D hybrid layers [Cu2I2(Hgtsc)]n and solvent molecules (DMF). Strong luminescence can be detected and interestingly, thermochromic behavior can be observed.

Graphical abstract: An organic–inorganic hybrid heterobridging luminescent copper(i) polymer exhibiting thermochromic behavior

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CE00754D
Article type
Communication
Submitted
04 Nov 2010
Accepted
04 Jan 2011
First published
20 Jan 2011

CrystEngComm, 2011,13, 1778-1781

Permissions

Request permissions

An organic–inorganic hybrid heterobridging luminescent copper(I) polymer exhibiting thermochromic behavior

H. Li, Y. Wang, H. Dong, Z. Chen, Y. Wu, M. Wang and S. Huang, CrystEngComm, 2011, 13, 1778 DOI: 10.1039/C0CE00754D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements