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Issue 42, 2011
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Amino acid functionalized metal–organic frameworks by a soft coupling–deprotection sequence

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Abstract

Covalent post-synthetic modification of a MOF, (In) MIL-68-NH2, is carried out in a novel fashion to immobilize amino acids within the structure. Solid-phase peptide coupling methodology opens new perspectives for anchoring chiral bio- and catalytically active species. This could facilitate the immobilization of highly active and/or coordinating moieties inside MOF cavities.

Graphical abstract: Amino acid functionalized metal–organic frameworks by a soft coupling–deprotection sequence

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Publication details

The article was received on 07 Sep 2011, accepted on 21 Sep 2011 and first published on 30 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC15541E
Chem. Commun., 2011,47, 11650-11652

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    Amino acid functionalized metal–organic frameworks by a soft coupling–deprotection sequence

    J. Canivet, S. Aguado, G. Bergeret and D. Farrusseng, Chem. Commun., 2011, 47, 11650
    DOI: 10.1039/C1CC15541E

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