Issue 42, 2011
From the journal:

Chemical Communications

Highly active iridium(i) complexes for the selective hydrogenation of carbon–carbon multiple bonds†

Linsey S. Bennie,a   Calum J. Fraser,a   Stephanie Irvine,a   William J. Kerr,*a   Shalini Anderssonb  and  Göran N. Nilssonb  

* Corresponding authors

a Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, 295 Cathedral Street, Glasgow, Scotland, UK
E-mail: w.kerr@strath.ac.uk
Fax: +44 141 548 4822
Tel: +44 141 548 2959

b Medicinal Chemistry, AstraZeneca, R&D Mölndal, SE-431 83 M, Sweden

Abstract

New iridium(I) complexes, bearing a bulky NHC/phosphine ligand combination, have been established as extremely efficient hydrogenation catalysts that can be used at low catalyst loadings, and are compatible with functional groups which are often sensitive to more routinely employed hydrogenation methods.

Graphical abstract: Highly active iridium(i) complexes for the selective hydrogenation of carbon–carbon multiple bonds

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Article information

DOI
https://doi.org/10.1039/C1CC14367K
Article type
Communication
Submitted
19 Jul 2011
Accepted
09 Sep 2011
First published
29 Sep 2011

Chem. Commun., 2011,47, 11653-11655

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Highly active iridium(I) complexes for the selective hydrogenation of carbon–carbon multiple bonds

L. S. Bennie, C. J. Fraser, S. Irvine, W. J. Kerr, S. Andersson and G. N. Nilsson, Chem. Commun., 2011, 47, 11653 DOI: 10.1039/C1CC14367K

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