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The synthesis and binding investigations of first generation C3v-symmetrical hydrogen bonding urea-amide based tripodal receptors, 1–6, with various anions such as acetate, phosphate, sulfate and chloride in DMSO-d6 are presented. Analysis of the 1H NMR titrations of 1–6 showed on all occasions the selective formation of 1 : 1 stoichiometries.

Graphical abstract: Selective and tuneable recognition of anions using C3v-symmetrical tripodal urea-amide receptor platforms

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