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Issue 36, 2011
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A mesoporous metal–organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra

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Abstract

The mesoporous framework [Cu3(L)(H2O)3]·(DMF)35·(H2O)35 (NOTT-119) shows on desolvation a BET surface area of 4118(200) m2 g−1, a pore volume of 2.35 cm3 g−1, a total H2 uptake of 101 mg g−1 at 60 bar, 77 K and a total CH4 uptake of 327 mg g−1 at 80 bar, 298 K.

Graphical abstract: A mesoporous metal–organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra

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Supplementary files

Article information


Submitted
30 May 2011
Accepted
11 Jul 2011
First published
09 Aug 2011

Chem. Commun., 2011,47, 9995-9997
Article type
Communication

A mesoporous metal–organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra

Y. Yan, S. Yang, A. J. Blake, W. Lewis, E. Poirier, S. A. Barnett, N. R. Champness and M. Schröder, Chem. Commun., 2011, 47, 9995
DOI: 10.1039/C1CC13170B

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