Issue 2, 2011
From the journal:

Chemical Communications

Stepwise assembly of two 3d–4d heterometallic coordination polymers based on a hexanuclear silver(i) metalloligand†

Di Sun,a   Dan-Feng Wang,a   Xi-Guang Han,a   Na Zhang,a   Rong-Bin Huang*a  and  Lan-Sun Zhengab  

* Corresponding authors

a Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
E-mail: rbhuang@xmu.edu.cn

b State key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, China

Abstract

Two novel 3d–4d heterometallic coordination polymers {[Cu3(bipy)3(H2O)5][Ag6(mna)6]·11.5H2O}n (1) and {[Zn3(eda)3(H2O)4][Ag6(mna)6]·8H2O}n (2) were synthesized based on a hexanuclear silver(I) metalloligand by a three-step synthetic method (bipy = 2, 2′-bipyridine, eda = ethylenediamine and H2mna = 2-mercaptonicotinic acid). The photoluminescence behaviors of 1 and 2 were also discussed.

Graphical abstract: Stepwise assembly of two 3d–4d heterometallic coordination polymers based on a hexanuclear silver(i) metalloligand

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Article information

DOI
https://doi.org/10.1039/C0CC03534C
Article type
Communication
Submitted
29 Aug 2010
Accepted
07 Oct 2010
First published
11 Nov 2010

Chem. Commun., 2011,47, 746-748

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Stepwise assembly of two 3d–4d heterometallic coordination polymers based on a hexanuclear silver(I) metalloligand

D. Sun, D. Wang, X. Han, N. Zhang, R. Huang and L. Zheng, Chem. Commun., 2011, 47, 746 DOI: 10.1039/C0CC03534C

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