Issue 2, 2011

Cobalt carbaporphyrin-catalyzed cyclopropanation

Abstract

Cobalt complexes of N-confused porphyrins and benziphthalocyanine, which both feature organometallic bonds at the macrocycle cores, catalyze the cyclopropanation of styrene with a higher trans-selectivity than the corresponding porphyrin and phthalocyanine complexes.

Graphical abstract: Cobalt carbaporphyrin-catalyzed cyclopropanation

Supplementary files

Article information

Article type
Communication
Submitted
15 Sep 2010
Accepted
18 Oct 2010
First published
11 Nov 2010

Chem. Commun., 2011,47, 749-751

Cobalt carbaporphyrin-catalyzed cyclopropanation

K. B. Fields, J. T. Engle, S. Sripothongnak, C. Kim, X. P. Zhang and C. J. Ziegler, Chem. Commun., 2011, 47, 749 DOI: 10.1039/C0CC03894F

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