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Issue 1, 2011
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Gold(i)-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonates

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Abstract

The use of [XPhosAu(NCMe)]SbF6 in nitromethane at 100 °C allows the rapid and efficient formation of variously substituted dihydroquinolines, which can be subsequently converted into indoles by a rare photochemical rearrangement.

Graphical abstract: Gold(i)-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonates

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Article information


Submitted
19 Feb 2010
Accepted
26 Mar 2010
First published
21 Apr 2010

Chem. Commun., 2011,47, 218-220
Article type
Communication

Gold(I)-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonates

C. Gronnier, Y. Odabachian and F. Gagosz, Chem. Commun., 2011, 47, 218
DOI: 10.1039/C0CC00033G

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