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Issue 1, 2011
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A triangulopalladium cluster consisting of μ3-capping silyl ligands

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Abstract

We report on the utility of multifunctional, κ1Si3S-coordinated tris(methimazolyl)silanide ligands [Si(mtMe)3] for the stabilisation of a triangulopalladium cluster [Pd3{Si(mtMe)3}2] (3) consisting of very unusual μ3-capping SiR3 donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.

Graphical abstract: A triangulopalladium cluster consisting of μ3-capping silyl ligands

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Publication details

The article was received on 04 Feb 2010, accepted on 14 Apr 2010 and first published on 28 Apr 2010


Article type: Communication
DOI: 10.1039/C002435J
Citation: Chem. Commun., 2011,47, 221-223

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    A triangulopalladium cluster consisting of μ3-capping silyl ligands

    F. Armbruster, J. Meyer, A. Baldes, P. O. Burgos, I. Fernández and F. Breher, Chem. Commun., 2011, 47, 221
    DOI: 10.1039/C002435J

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