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Issue 29, 2011
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Hydroboration of an alkene by amine–boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation

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Abstract

The catalytic hydroboration of tert-butylethene using H3B·NMe3 gives RH2B·NMe3. With H3B·NMe2H tandem hydroboration under mild conditions/dehydrocoupling occurs that produces R2B[double bond, length as m-dash]NMe2 (R = H, CH2CH2tBu).

Graphical abstract: Hydroboration of an alkene by amine–boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation

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Article information


Submitted
03 May 2011
Accepted
02 Jun 2011
First published
29 Jun 2011

Dalton Trans., 2011,40, 7499-7501
Article type
Communication

Hydroboration of an alkene by amineboranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation

L. J. Sewell, A. B. Chaplin and A. S. Weller, Dalton Trans., 2011, 40, 7499
DOI: 10.1039/C1DT10819K

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