Issue 29, 2011

Structure and properties of an eight-coordinate Mn(ii) complex that demonstrates a high water relaxivity

Abstract

An air-stable eight-coordinate (8C) Mn(II)N8 complex has been synthesized utilizing an N4imidazole/imine ligand. The 8C dodecahedral geometry is structurally robust as the Mn complex is stable to air, NO(g), and potential coordinating anions. The structural, spectroscopic and water relaxivity properties of this complex are reported.

Graphical abstract: Structure and properties of an eight-coordinate Mn(ii) complex that demonstrates a high water relaxivity

Supplementary files

Article information

Article type
Communication
Submitted
05 Apr 2011
Accepted
27 May 2011
First published
24 Jun 2011

Dalton Trans., 2011,40, 7496-7498

Structure and properties of an eight-coordinate Mn(II) complex that demonstrates a high water relaxivity

K. S. Dube and T. C. Harrop, Dalton Trans., 2011, 40, 7496 DOI: 10.1039/C1DT10579E

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