Issue 29, 2011
From the journal:

Dalton Transactions

Structure and properties of an eight-coordinate Mn(ii) complex that demonstrates a high water relaxivity†

Koustubh S. Dubea  and  Todd C. Harrop*a  

* Corresponding authors

a Department of Chemistry, The University of Georgia, 1001 Cedar Street, Athens, GA, USA
E-mail: tharrop@uga.edu
Fax: +1-706-542-9454
Tel: +1-706-542-3486

Abstract

An air-stable eight-coordinate (8C) Mn(II)N8 complex has been synthesized utilizing an N4imidazole/imine ligand. The 8C dodecahedral geometry is structurally robust as the Mn complex is stable to air, NO(g), and potential coordinating anions. The structural, spectroscopic and water relaxivity properties of this complex are reported.

Graphical abstract: Structure and properties of an eight-coordinate Mn(ii) complex that demonstrates a high water relaxivity

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Article information

DOI
https://doi.org/10.1039/C1DT10579E
Article type
Communication
Submitted
05 Apr 2011
Accepted
27 May 2011
First published
24 Jun 2011

Dalton Trans., 2011,40, 7496-7498

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Structure and properties of an eight-coordinate Mn(II) complex that demonstrates a high water relaxivity

K. S. Dube and T. C. Harrop, Dalton Trans., 2011, 40, 7496 DOI: 10.1039/C1DT10579E

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