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Issue 47, 2011
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Non-classical heteroacenes: synthesis and properties of anthra[2,3-c:6,7-c′]dithiophene derivatives

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Abstract

A new class of linear heteroacenes, anthra[2,3-c:6,7-c′]dithiophenes, containing non-classical (non-Kekulé) thiophene in a 22-electron π-conjugated system have been prepared by electrochemical reduction. The electronic properties have been studied by DFT calculations and spectroelectrochemistry, supporting the formation of a triplet electronic structure.

Graphical abstract: Non-classical heteroacenes: synthesis and properties of anthra[2,3-c:6,7-c′]dithiophene derivatives

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Article information


Submitted
11 Sep 2011
Accepted
14 Oct 2011
First published
31 Oct 2011

Chem. Commun., 2011,47, 12619-12621
Article type
Communication

Non-classical heteroacenes: synthesis and properties of anthra[2,3-c:6,7-c′]dithiophene derivatives

B. Djukic and D. F. Perepichka, Chem. Commun., 2011, 47, 12619
DOI: 10.1039/C1CC15623C

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