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Issue 30, 2011
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Metallocenes@COF-102: organometallic host–guest chemistry of porous crystalline organic frameworks

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Abstract

The organometallic host–guest chemistry of porous covalent organic frameworks is explored by vapour phase infiltration of volatile organometallic precursors; namely, [Fe(η5-C5H5)2], [Co(η5-C5H5)2], and [Ru(cod)(cot)]. The unique arrangement of ferrocene molecules inside COF-102 is driven by π–π (host–guest) interactions and replicates the framework symmetry.

Graphical abstract: Metallocenes@COF-102: organometallic host–guest chemistry of porous crystalline organic frameworks

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Publication details

The article was received on 13 Mar 2011, accepted on 29 Mar 2011 and first published on 18 Apr 2011


Article type: Communication
DOI: 10.1039/C1CC11450F
Chem. Commun., 2011,47, 8506-8508

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    Metallocenes@COF-102: organometallic host–guest chemistry of porous crystalline organic frameworks

    S. B. Kalidindi, K. Yusenko and R. A. Fischer, Chem. Commun., 2011, 47, 8506
    DOI: 10.1039/C1CC11450F

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