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A novel copper-catalyzed aminobromination-elimination process has been developed, which provides an easy access to α,β-unsaturated vicinal haloamindes derivatives from readily available α,β-unsaturated ketones and esters in good to excellent yields. The isolated intermediate discloses that the current system proceeds through the aminobromination process.

Graphical abstract: Copper-catalyzed aminobromination/elimination process: an efficient access to α,β-unsaturated vicinal haloamino ketones and esters

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