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Issue 32, 2010
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Imidazolium-based ionic liquids immobilized on solid supports: effect on the structure and thermostability

Laura Rodríguez-Pérez,ab  Yannick Coppel,b  Isabelle Favier,a  Emmanuelle Teuma,a  Philippe Serpb  and  Montserrat Gómez*a 
Author affiliations

* Corresponding authors

a Université Paul Sabatier, Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, 118, route de Narbonne, 31062 Toulouse cedex 9, France
E-mail: gomez@chimie.ups-tlse.fr
Fax: + 33 561558204
Tel: + 33 561557734

b LCC (Laboratoire de Chimie de Coordination) – composante ENSIACET, 118, route de Narbonne, 31077 Toulouse, France

Abstract

[BMI][PF6] has been supported on silica and alumina in order to study the effect of these classical oxide supports on the structure of the ionic liquid. A widespread characterization by TGA, DSC, XRD and solid NMR of thin films of [BMI][PF6] immobilized on these amorphous supports has evidenced a dramatic effect on the ionic liquid structure depending on the nature of the support. For the alumina composite, a loss of the supramolecular arrangement of the ionic liquid occurs, while for the analogous silica composite, ions interact strongly with the support, leading to a [BMI][PF6] thermostability decrease.

Graphical abstract: Imidazolium-based ionic liquids immobilized on solid supports: effect on the structure and thermostability

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Publication details

The article was received on 30 Apr 2010, accepted on 01 Jun 2010 and first published on 09 Jul 2010


Article type: Paper
DOI: 10.1039/C0DT00397B
Citation: Dalton Trans., 2010,39, 7565-7568
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    Imidazolium-based ionic liquids immobilized on solid supports: effect on the structure and thermostability

    L. Rodríguez-Pérez, Y. Coppel, I. Favier, E. Teuma, P. Serp and M. Gómez, Dalton Trans., 2010, 39, 7565
    DOI: 10.1039/C0DT00397B

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