Hydroboration of dimesitylvinylphosphine with Piers’ borane [HB(C6F5)2] gives the ethylene-bridged intramolecular frustrated P/B Lewis pair 1. It adds pyridine, tert-butyl isocyanide or pivalonitrile to the strongly electrophilic boron center to yield the respective adducts 5–7. Compound 1 undergoes a 1,1-phosphine/borane addition to the terminal nitrogen center of phenyl azide to yield the five-membered heterocycle 8, featuring a pendant –N
N–Ph. This can be regarded as a boron-stabilized intermediate of a Staudinger reaction. Benzaldehyde and phenyl isocyanate undergo 1,2-P/B additions of 1 to their reactive carbonyl groups to yield the corresponding six-membered heterocycles 9 and 10, respectively. The P/B Lewis pair reacts with nitrosobenzene by 1,2-addition to the –N
O unit under P–N and O–B bond formation to give the six-membered heterocycle 11. The compounds 5–11 were characterized by X-ray crystal structure analyses.
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