Issue 5, 2010
From the journal:

Dalton Transactions

One-dimensional metal-azido complex constructed by a double EO azido bridged trinuclear nickel(ii) unit: synthesis, structure and magnetic properties†‡§

Fu-Chen Liu,ab   Jiong-Peng Zhao,a   Bo-Wen Hu,a   Yong-Fei Zeng,a   J. Ribasc  and  Xian-He Bu*a  

* Corresponding authors

a Department of Chemistry, Nankai University, Tianjin 300071, China
E-mail: buxh@nankai.edu.cn
Fax: +86-22-23502458
Tel: +86-22-23502809

b School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300191, China

c Departament de Química Inorgànica Universitat de Barcelona, Diagonal, 6487, Spain

Abstract

The hydrothermal reaction of Ni(NO3)2·6H2O, NaN3 phenanthroline and nicotinic acid yielded a one-dimensional (1D) complex, [Ni1.5(N3)2(phen)(nic)]n (1) (phen = phenanthroline, nic = nicotinate), which is a new example of the named orbital countercomplementarity-like complex. In 1, the nicotinate shows μ3-nic-N,O,O coordination mode, and the azide groups adopt μ1,1 bridging mode linking NiII ions to form a rare trinuclear NiII unit bridged by a double μ1,1 azido.

Graphical abstract: One-dimensional metal-azido complex constructed by a double EO azido bridged trinuclear nickel(ii) unit: synthesis, structure and magnetic properties

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Article information

DOI
https://doi.org/10.1039/B915616J
Article type
Communication
Submitted
30 Jul 2009
Accepted
23 Oct 2009
First published
05 Nov 2009

Dalton Trans., 2010,39, 1185-1187

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One-dimensional metal-azido complex constructed by a double EO azido bridged trinuclear nickel(II) unit: synthesis, structure and magnetic properties

F. Liu, J. Zhao, B. Hu, Y. Zeng, J. Ribas and X. Bu, Dalton Trans., 2010, 39, 1185 DOI: 10.1039/B915616J

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