Issue 7, 2010
From the journal:

CrystEngComm

Spontaneous resolution of two homochiral ferroelectric cadmium(ii) frameworks and an achiral framework from a one-pot reaction involving achiral rigid ligands†

Zhi Su,a   Man-Sheng Chen,a   Jian Fan,a   Min Chen,a   Shui-Sheng Chen,a   Li Luoa  and  Wei-Yin Sun*a  

* Corresponding authors

a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing, China
E-mail: sunwy@nju.edu.cn
Fax: +86 25 8331 4502

Abstract

Unprecedented two homochiral Cd(II) enantiomers and one achiral Cd(II) complex obtained from one pot reaction with achiral mixed rigid ligands 1,3,5-tris(1-imidazolyl)benzene (tib) and 1,4-benzenedicarboxylate (BDC2−) feature interesting entangled structures in which the ligands display huge distortion, and the homochiral enantiomers show ferroelectric property.

Graphical abstract: Spontaneous resolution of two homochiral ferroelectric cadmium(ii) frameworks and an achiral framework from a one-pot reaction involving achiral rigid ligands

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Article information

DOI
https://doi.org/10.1039/C0CE00054J
Article type
Communication
Submitted
23 Dec 2009
Accepted
08 Apr 2010
First published
05 May 2010

CrystEngComm, 2010,12, 2040-2043

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Spontaneous resolution of two homochiral ferroelectric cadmium(II) frameworks and an achiral framework from a one-pot reaction involving achiral rigid ligands

Z. Su, M. Chen, J. Fan, M. Chen, S. Chen, L. Luo and W. Sun, CrystEngComm, 2010, 12, 2040 DOI: 10.1039/C0CE00054J

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