Issue 7, 2010
From the journal:

CrystEngComm

Resolution of chiral polyoxoanion [P2Mo18O62]6− with histidine†

Ding Liu,a   Hua-Qiao Tan,a   Wei-Lin Chen,a   Yang-Guang Li*a  and  En-Bo Wang*a  

* Corresponding authors

a Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Ren Min Street No. 5268, Changchun, Jilin, P. R. China
E-mail: wangeb889@nenu.edu.cn, liyg658@nenu.edu.cn.
Fax: +86-431-85098787

Abstract

The classical Dawson-type racemic polyoxoanions [P2Mo18O62]6− have been separated in aqueous solution with L,D-histidine, respectively. Two enantiomerically pure compounds: H3(L-HC6H9N3O2)3[P2Mo18O62]·20H2O (1a), H3(D-HC6H9N3O2)3[P2Mo18O62]·20H2O (1b), have been synthesized.

Graphical abstract: Resolution of chiral polyoxoanion [P2Mo18O62]6− with histidine

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Article information

DOI
https://doi.org/10.1039/C001160F
Article type
Communication
Submitted
19 Jan 2010
Accepted
09 Mar 2010
First published
11 May 2010

CrystEngComm, 2010,12, 2044-2046

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Resolution of chiral polyoxoanion [P2Mo18O62]6− with histidine

D. Liu, H. Tan, W. Chen, Y. Li and E. Wang, CrystEngComm, 2010, 12, 2044 DOI: 10.1039/C001160F

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