Issue 28, 2010
From the journal:

Chemical Communications

Cerberus-type N-heterocyclic carbenes: synthesis and study of the first tritopic carbenes with D3h-symmetry†

Kyle A. Williamsa  and  Christopher W. Bielawski*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, USA
E-mail: bielawski@cm.utexas.edu

Abstract

The synthesis and characterization of tris(N-heterocyclic carbene)s with D3h-symmetry is reported; these tritopic molecules feature three independent carbene moieties that are geometrically isolated to prevent chelation.

Graphical abstract: Cerberus-type N-heterocyclic carbenes: synthesis and study of the first tritopic carbenes with D3h-symmetry

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Article information

DOI
https://doi.org/10.1039/C0CC01070G
Article type
Communication
Submitted
22 Apr 2010
Accepted
21 May 2010
First published
08 Jun 2010

Chem. Commun., 2010,46, 5166-5168

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Cerberus-type N-heterocyclic carbenes: synthesis and study of the first tritopic carbenes with D3h-symmetry

K. A. Williams and C. W. Bielawski, Chem. Commun., 2010, 46, 5166 DOI: 10.1039/C0CC01070G

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