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Issue 35, 2010
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Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(ii) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

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Abstract

[FeII(C16dpt)2(NCS)2]·⅔H2O displays temperature-mediated spin crossover (SCO) with T½ = 290 K and the long alkyl chain substituent on the dipyridyltriazole ligand facilitates the formation of a stable Langmuir–Blodgett film at an air–water interface.

Graphical abstract: Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(ii) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

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Article information


Submitted
19 Apr 2010
Accepted
17 Jun 2010
First published
07 Jul 2010

Chem. Commun., 2010,46, 6464-6466
Article type
Communication

Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(II) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

J. A. Kitchen, N. G. White, C. Gandolfi, M. Albrecht, G. N. L. Jameson, J. L. Tallon and S. Brooker, Chem. Commun., 2010, 46, 6464
DOI: 10.1039/C0CC01008A

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