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Issue 35, 2010
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Nuclearity of nickel and mixed sodiumnickel complexes: dependence on the spacer in chelating pyridine-alcoholate ligands

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Abstract

Modifying the HL/Ni(II) stoichiometry in the reaction between pyridine-2-ylmethanol (HL), [NiCl2(DME)] and NaH affords [Na3Ni4L93-OH)]Cl (1) or the new, unusual Na10Ni6 polynuclear complex [Na8(NaL)2(NiL3)65-OH)2] (2); starting from pyridine-2-ylethanol (HLEt) instead yielded [Ni3(μ-LEt)23-LEt)2(LEt)(HLEt)]Cl, whose magnetic properties are reported.

Graphical abstract: Nuclearity of nickel and mixed sodium–nickel complexes: dependence on the spacer in chelating pyridine-alcoholate ligands

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Publication details

The article was received on 15 May 2010, accepted on 07 Jul 2010 and first published on 10 Aug 2010


Article type: Communication
DOI: 10.1039/C0CC01425G
Citation: Chem. Commun., 2010,46, 6461-6463

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    Nuclearity of nickel and mixed sodiumnickel complexes: dependence on the spacer in chelating pyridine-alcoholate ligands

    L. Kayser, R. Pattacini, G. Rogez and P. Braunstein, Chem. Commun., 2010, 46, 6461
    DOI: 10.1039/C0CC01425G

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