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Issue 35, 2010
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Single molecule magnet behaviour in robust dysprosium–biradical complexes

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Abstract

A Dy–biradical complex was synthesized and characterized down to very low temperature. ac magnetic measurements reveal single molecule magnet behaviour visible without any application of dc field. The transition to the quantum tunneling regime is evidenced. Photophysical and EPR measurements provide evidence of the excellent stability of these complexes in solution.

Graphical abstract: Single molecule magnet behaviour in robust dysprosium–biradical complexes

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Publication details

The article was received on 15 Apr 2010, accepted on 20 Jul 2010 and first published on 17 Aug 2010


Article type: Communication
DOI: 10.1039/C0CC00966K
Citation: Chem. Commun., 2010,46, 6458-6460

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    Single molecule magnet behaviour in robust dysprosium–biradical complexes

    K. Bernot, F. Pointillart, P. Rosa, M. Etienne, R. Sessoli and D. Gatteschi, Chem. Commun., 2010, 46, 6458
    DOI: 10.1039/C0CC00966K

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