Issue 15, 2010

Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials

Abstract

A new chiral open-framework cobalt phosphite [C6N2H14][Co(HPO3)2] (1) with helical channels has been synthesized under solvothermal conditions in the presence of achiral organic amine. The circular dichroism (CD) spectrum indicates that the bulk crystals have optical activity. Magnetic measurements reveal that 1 is a weak ferromagnet.

Graphical abstract: Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials

Supplementary files

Article information

Article type
Communication
Submitted
03 Nov 2009
Accepted
05 Feb 2010
First published
24 Feb 2010

Chem. Commun., 2010,46, 2614-2616

Chirality and magnetism of an open-framework cobalt phosphite containing helical channels from achiral materials

X. Liu, Y. Xing, X. Wang, H. Xu, X. Liu, K. Shao and Z. Su, Chem. Commun., 2010, 46, 2614 DOI: 10.1039/B923028A

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