Chemisorption of fluorous copper(II)-carboxylate complexes on SiO2 surfaces: versatile binding layers applied to the preparation of porphyrin monolayers

Artur Motreff; Guillaume Raffy; André Del Guerzo; Colette Belin; Marc Dussauze; Vincent Rodriguez; Jean-Marc Vincent

doi:10.1039/B923525F

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Chemisorption of fluorous copper(ii)-carboxylate complexes on SiO₂ surfaces: versatile binding layers applied to the preparation of porphyrin monolayers†

Artur Motreff,^a Guillaume Raffy,^a André Del Guerzo,^a Colette Belin,^a Marc Dussauze,^a Vincent Rodriguez^a and Jean-Marc Vincent*^a

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* Corresponding authors

^a University Bordeaux 1, CNRS, Institut des Sciences Moléculaires, 33405 Talence Cedex, France
E-mail: jm.vincent@ism.u-bordeaux1.fr

Abstract

The fluorous copper(II)-carboxylate complexes 1 and 2 are readily chemisorbed on SiO₂ surfaces affording super-hydrophilic binding layers for subsequent versatile functionalization by coordination chemistry.

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Synthetic procedures and full experimental data PDF (1292K)

Article information

DOI: https://doi.org/10.1039/B923525F
Article type: Communication
Submitted: 10 Nov 2009
Accepted: 21 Jan 2010
First published: 09 Feb 2010

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Chem. Commun., 2010,46, 2617-2619

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Chemisorption of fluorous copper(II)-carboxylate complexes on SiO₂ surfaces: versatile binding layers applied to the preparation of porphyrin monolayers

A. Motreff, G. Raffy, A. Del Guerzo, C. Belin, M. Dussauze, V. Rodriguez and J. Vincent, Chem. Commun., 2010, 46, 2617 DOI: 10.1039/B923525F

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