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Issue 1, 2010
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Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

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Abstract

Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA·K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA·K(μ-Me)2Zn(Fc)}] and [{PMDETA·K(μ-Me)2Zn(Rc)}2], respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

Graphical abstract: Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

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Article information


Submitted
13 May 2009
Accepted
16 Sep 2009
First published
30 Sep 2009

Dalton Trans., 2010,39, 62-65
Article type
Communication

Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

W. Clegg, B. Conway, P. García-Álvarez, A. R. Kennedy, J. Klett, R. E. Mulvey and L. Russo, Dalton Trans., 2010, 39, 62
DOI: 10.1039/B917202P

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