Jump to main content
Jump to site search

Issue 1, 2010
Previous Article Next Article

Stepwise assembly of a bis-hydroxylaminato galliumindium complex

Author affiliations

Abstract

A heterobimetallic galliumindium complex with five-coordinate InMe group bonded via two O and two N atoms to a [GaR2ON(Me)(CH2)2N(Me)O]2 macrocycle resulted from the reaction of the OH- and NH-functional bishydroxylaminato complex of gallium, MeN(OH)(CH2)2N(H)(Me)OGaR2O-cyclo[N(Me)(CH2)2N(Me)OGaR2] (R = tBu) with InMe3, whereas the reaction of the latter with Me3N·AlH3 affords a gallium hydride with Ga–Ga bonds.

Graphical abstract: Stepwise assembly of a bis-hydroxylaminato gallium–indium complex

Back to tab navigation

Supplementary files

Publication details

The article was received on 01 Jul 2009, accepted on 14 Sep 2009 and first published on 24 Sep 2009


Article type: Communication
DOI: 10.1039/B913016K
Citation: Dalton Trans., 2010,39, 66-69

  •   Request permissions

    Stepwise assembly of a bis-hydroxylaminato galliumindium complex

    P. Bösing and N. W. Mitzel, Dalton Trans., 2010, 39, 66
    DOI: 10.1039/B913016K

Search articles by author

Spotlight

Advertisements