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Issue 31, 2010
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Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes

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Abstract

The reactivity of heterobimetallic Zr/Co complexes linked by phosphinoamide ligands towards the oxidative addition of I2 and alkyl halides is reported. These reactions are accompanied by dissociation of one phosphine ligand from Co and η2-coordination to Zr. Addition of H2 leads to both oxidative addition across the M–M bond and P–N bond cleavage.

Graphical abstract: Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes

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Article information


Submitted
07 May 2010
Accepted
10 Jun 2010
First published
24 Jun 2010

Chem. Commun., 2010,46, 5790-5792
Article type
Communication

Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes

C. M. Thomas, J. W. Napoline, G. T. Rowe and B. M. Foxman, Chem. Commun., 2010, 46, 5790
DOI: 10.1039/C0CC01272F

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