Issue 2, 2009
From the journal:

Dalton Transactions

Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes†

Raquel Gracia,a   Harry Adamsa  and  Nathan J. Patmore*a  

* Corresponding authors

a Department of Chemistry, University of Sheffield, Sheffield, UK
E-mail: n.patmore@sheffield.ac.uk.
Tel: +44 (0) 114 222 9418

Abstract

The Ru–Ru bond length for Ru2II,III and Ru2II,II paddlewheel complexes containing the bulky carboxylate ligand 2,4,6-triisopropylbenzoate was found to decrease despite a reduction in Ru–Ru bond order, due to increased internal rotation.

Graphical abstract: Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B820287G
Article type
Communication
Submitted
12 Nov 2008
Accepted
14 Nov 2008
First published
26 Nov 2008

Dalton Trans., 2009, 259-261

Permissions

Request permissions

Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes

R. Gracia, H. Adams and N. J. Patmore, Dalton Trans., 2009, 259 DOI: 10.1039/B820287G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements