Issue 2, 2009
From the journal:

Dalton Transactions

Recent developments in the coordination chemistry of bis(imino)acenaphthene (BIAN) ligands with s- and p-block elements

Nicholas J. Hill,a   Ignacio Vargas-Bacab  and  Alan H. Cowley*c  

* Corresponding authors

a Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI, USA
E-mail: njhill@wisc.edu
Fax: +1 608 265 4534
Tel: +1 608 262 2306

b On leave from Department of Chemistry, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada
E-mail: vargas@chemistry.mcmaster.ca
Fax: +1 905 522 2509
Tel: +1 905 525 9140 ext. 23497

c Department of Chemistry and Biochemistry, University of Texas at Austin, 1 University Station, Austin, TX
E-mail: cowley@mail.utexas.edu
Tel: +1 512 471 7484

Abstract

Bis(imino)acenaphthenes (BIAN) have been known for many years. However, it is only since the 1990s that such compounds have been recognized as robust ligands for the support of catalytically active transition metal centers. More recently, the unique stereoelectronic properties of the BIAN ligand class are beginning to be appreciated and exploited for some fascinating new developments in synthetic, structural and catalytic s- and p-block chemistry.

Graphical abstract: Recent developments in the coordination chemistry of bis(imino)acenaphthene (BIAN) ligands with s- and p-block elements

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Article information

DOI
https://doi.org/10.1039/B815079F
Article type
Perspective
Submitted
11 Sep 2008
Accepted
03 Oct 2008
First published
12 Nov 2008

Dalton Trans., 2009, 240-253

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Recent developments in the coordination chemistry of bis(imino)acenaphthene (BIAN) ligands with s- and p-block elements

N. J. Hill, I. Vargas-Baca and A. H. Cowley, Dalton Trans., 2009, 240 DOI: 10.1039/B815079F

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