Issue 44, 2009
From the journal:

Chemical Communications

Primary amine-metal Lewis acid bifunctional catalysts: the application to asymmetric direct aldol reactions†

Zhenghu Xu,a   Philias Dakaa  and  Hong Wang*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Miami University, Oxford
E-mail: wangh3@muohio.edu
Fax: +1 (513)529-2824
Tel: +1 (513)529-2824

Abstract

The first example of metal Lewis acid-primary amine bifunctional cooperative catalyst derived from primary amino acids was developed, and it was found to catalyze aldol reactions of cyclic ketones highly efficiently with very good to excellent stereoselectivities.

Graphical abstract: Primary amine-metal Lewis acid bifunctional catalysts: the application to asymmetric direct aldol reactions

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Article information

DOI
https://doi.org/10.1039/B912728C
Article type
Communication
Submitted
02 Jul 2009
Accepted
18 Sep 2009
First published
07 Oct 2009

Chem. Commun., 2009, 6825-6827

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Primary amine-metal Lewis acid bifunctional catalysts: the application to asymmetric direct aldol reactions

Z. Xu, P. Daka and H. Wang, Chem. Commun., 2009, 6825 DOI: 10.1039/B912728C

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