Issue 44, 2009

Evidence for the formation of a mononuclear ferric–hydroperoxo complex via the reaction of dioxygen with an (N4S(thiolate))iron(ii) complex

Abstract

Addition of O2(g) at low-temperature to a mononuclear, nonheme iron(II) complex comprising a tetraazamacrocyclic N4 donor and an arylthiolate S donor leads to the generation of a deep red complex assigned as a low-spin FeIII–OOH complex, formed via metal- and ligand-assisted oxidation.

Graphical abstract: Evidence for the formation of a mononuclear ferric–hydroperoxo complex via the reaction of dioxygen with an (N4S(thiolate))iron(ii) complex

Supplementary files

Article information

Article type
Communication
Submitted
13 Jul 2009
Accepted
15 Sep 2009
First published
13 Oct 2009

Chem. Commun., 2009, 6828-6830

Evidence for the formation of a mononuclear ferric–hydroperoxo complex via the reaction of dioxygen with an (N4S(thiolate))iron(II) complex

Y. Jiang, J. Telser and D. P. Goldberg, Chem. Commun., 2009, 6828 DOI: 10.1039/B913945A

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