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Issue 40, 2009
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Iridium-catalyzed enantioselective hydrogenation of vinyl boronates

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Abstract

The first Ir-catalyzed asymmetric hydrogenations of vinyl boronates have been performed using low catalyst loadings (0.5 mol%) and pressure (as low as 1 bar). Good selectivities (76–98% ee) were obtained for a range of substrates.

Graphical abstract: Iridium-catalyzed enantioselective hydrogenation of vinyl boronates

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Publication details

The article was received on 25 Jun 2009, accepted on 24 Aug 2009 and first published on 15 Sep 2009


Article type: Communication
DOI: 10.1039/B912590F
Citation: Chem. Commun., 2009,0, 5996-5998
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    Iridium-catalyzed enantioselective hydrogenation of vinyl boronates

    A. Paptchikhine, P. Cheruku, M. Engman and P. G. Andersson, Chem. Commun., 2009, 0, 5996
    DOI: 10.1039/B912590F

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