Issue 36, 2009
From the journal:

Chemical Communications

Towards enzyme-like enantioselectivity in the gas phase: conformational control of selectivity in chiral macrocyclic dimers†

Caterina Fraschetti,a   Marco Pierini,a   Claudio Villani,*a   Francesco Gasparrini,a   Stefano Levi Morteraa  and  Maurizio Speranza*a  

* Corresponding authors

a Dipartimento di Chimica e Tecnologie del Farmaco, Università di Roma “La Sapienza”, Rome, Italy
E-mail: maurizio.speranza@ uniroma1.it
Fax: +39-06-49913497
Tel: +39-06-49913602

Abstract

Conformational factors in self-assembled chiral tetraamide macrocycles control their gas-phase enantioselectivity towards the ethyl ester of naphthylalanine to levels typical of enzymes.

Graphical abstract: Towards enzyme-like enantioselectivity in the gas phase: conformational control of selectivity in chiral macrocyclic dimers

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Article information

DOI
https://doi.org/10.1039/B909017G
Article type
Communication
Submitted
06 May 2009
Accepted
13 Jul 2009
First published
31 Jul 2009

Chem. Commun., 2009, 5430-5432

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Towards enzyme-like enantioselectivity in the gas phase: conformational control of selectivity in chiral macrocyclic dimers

C. Fraschetti, M. Pierini, C. Villani, F. Gasparrini, S. L. Mortera and M. Speranza, Chem. Commun., 2009, 5430 DOI: 10.1039/B909017G

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