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Issue 10, 2009
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Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds

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Abstract

Reactions of a neutral silyleneruthenium complex with ketones and aldehydes, and isolation of their agostic intermediates are reported, where an α-H abstraction or hydrosilylation of the carbonyl compounds occurs depending on the substituents of the substrates.

Graphical abstract: Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds

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Article information


Submitted
29 Oct 2008
Accepted
19 Nov 2008
First published
27 Jan 2009

Dalton Trans., 2009, 1812-1814
Article type
Paper

Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds

M. Ochiai, H. Hashimoto and H. Tobita, Dalton Trans., 2009, 1812
DOI: 10.1039/B819229B

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