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Issue 16, 2009
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Hydride–bromide exchange at an NHC—a new route to brominated alanes and gallanes

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Abstract

The reaction of [MH3(Quinuclidine)] (M = Al or Ga) with an air stable dibrominated N-heterocyclic carbene (NHC) affords the hydride–bromide exchange product [MBr2H(NHC)].

Graphical abstract: Hydride–bromide exchange at an NHC—a new route to brominated alanes and gallanes

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Article information


Submitted
28 Nov 2008
Accepted
11 Feb 2009
First published
18 Feb 2009

Dalton Trans., 2009, 2909-2911
Article type
Communication

Hydride–bromide exchange at an NHC—a new route to brominated alanes and gallanes

S. G. Alexander, M. L. Cole, S. K. Furfari and M. Kloth, Dalton Trans., 2009, 2909
DOI: 10.1039/B821367D

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