Issue 16, 2009
From the journal:

Dalton Transactions

Synthesis of parent amido (NH2)-bridged dinuclear complexes of ruthenium and iridium by stepwise transfer hydrogenation of μ-azido complexes†

Takashi Kimura,a   Hiroko Arita,a   Koji Ishiwata,a   Shigeki Kuwata*a  and  Takao Ikariya*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, Japan
E-mail: skuwata@apc.titech.ac.jp, tikariya@apc.titech.ac.jp
Fax: +81 3 5734 2637
Tel: +81 3 5734 2636

Abstract

The azido-bridged diruthenium and diiridium complexes [(LMCl)2(μ-N3)2] (LM = CymRu, Cp*Ir; Cym = η6-p-cymene, Cp* = η5-C5(CH3)5) are sequentially converted into the amido-bridged complexes [(LMCl)2(μ-NH2)(μ-N3)] and [(LMCl)2(μ-NH2)(μ-H)] upon treatment with 2-propanol and a base.

Graphical abstract: Synthesis of parent amido (NH2)-bridged dinuclear complexes of ruthenium and iridium by stepwise transfer hydrogenation of μ-azido complexes

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Article information

DOI
https://doi.org/10.1039/B902810M
Article type
Communication
Submitted
10 Feb 2009
Accepted
16 Feb 2009
First published
26 Feb 2009

Dalton Trans., 2009, 2912-2914

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Synthesis of parent amido (NH2)-bridged dinuclear complexes of ruthenium and iridium by stepwise transfer hydrogenation of μ-azido complexes

T. Kimura, H. Arita, K. Ishiwata, S. Kuwata and T. Ikariya, Dalton Trans., 2009, 2912 DOI: 10.1039/B902810M

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