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Issue 4, 2009
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The first observation of a Na2TiS2 related structure in a 2-D anionic manganese trimesate intercalated by cationic imidazole,

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Abstract

A hydrothermal reaction of Mn(OAc)2·4H2O, trimesic acid, imidazole, KOH and water at 75 °C for 24 h gave rise to a 2-D compound, [HImd][Mn(BTC)(H2O)] (Imd = imidazole; BTC = trimesate), with protonated imidazole molecules occupying the inter-lamellar space, and the structure resembles the classic inorganic compound, the sodium intercalated TiS2 (Na2TiS2).

Graphical abstract: The first observation of a Na2TiS2 related structure in a 2-D anionic manganese trimesate intercalated by cationic imidazole,

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Publication details

The article was received on 12 Nov 2008, accepted on 17 Dec 2008 and first published on 27 Jan 2009


Article type: Communication
DOI: 10.1039/B820248F
CrystEngComm, 2009,11, 560-563

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    The first observation of a Na2TiS2 related structure in a 2-D anionic manganese trimesate intercalated by cationic imidazole,

    P. Mahata and S. Natarajan, CrystEngComm, 2009, 11, 560
    DOI: 10.1039/B820248F

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