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Issue 44, 2009
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In situreduction of Fe(iii) into Fe(ii): an example of post-crystallisation transformation

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Abstract

Upon exposing crystals made of a combination of an amidinium based dication and [FeIII(CN)6]3− anion to a hydroalcoholic solution of hydrazine and KCl, the reduction of Fe(III) to Fe(II) with concomitant incorporation of K+ cation takes place in the crystalline phase.

Graphical abstract: In situ reduction of Fe(iii) into Fe(ii): an example of post-crystallisation transformation

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Publication details

The article was received on 23 Jul 2009, accepted on 16 Sep 2009 and first published on 01 Oct 2009


Article type: Communication
DOI: 10.1039/B914964C
Chem. Commun., 2009, 6798-6800

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    In situ reduction of Fe(III) into Fe(II): an example of post-crystallisation transformation

    P. Dechambenoit, S. Ferlay, N. Kyritsakas and M. W. Hosseini, Chem. Commun., 2009, 6798
    DOI: 10.1039/B914964C

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