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Issue 5, 2009
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A [Mn18Dy] SMM resulting from the targeted replacement of the central MnII in the S = 83/2 [Mn19]-aggregate with DyIII

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Abstract

Anisotropy can be introduced into the [Mn19]-aggregate, which currently has the highest known spin ground state of S = 83/2, by the targeted replacement of the central MnII cation with DyIII leading to a [Mn18Dy] complex with the same core topology showing slow relaxation of the magnetisation.

Graphical abstract: A [Mn18Dy] SMM resulting from the targeted replacement of the central MnII in the S = 83/2 [Mn19]-aggregate with DyIII

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Article information


Submitted
21 Aug 2008
Accepted
03 Nov 2008
First published
27 Nov 2008

Chem. Commun., 2009, 544-546
Article type
Communication

A [Mn18Dy] SMM resulting from the targeted replacement of the central MnII in the S = 83/2 [Mn19]-aggregate with DyIII

A. M. Ako, V. Mereacre, R. Clérac, W. Wernsdorfer, I. J. Hewitt, C. E. Anson and A. K. Powell, Chem. Commun., 2009, 544
DOI: 10.1039/B814614D

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