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Issue 5, 2009
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Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

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Abstract

The well-defined conformation of an N,N′-diarylurea allows a chiral sulfinyl substituent to influence diastereoselectivity in the formation of new stereogenic centres up to 14 bond lengths away.

Graphical abstract: Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

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Publication details

The article was received on 06 Oct 2008, accepted on 10 Nov 2008 and first published on 26 Nov 2008


Article type: Communication
DOI: 10.1039/B817527F
Citation: Chem. Commun., 2009,0, 547-549
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    Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

    J. Clayden, M. Pickworth and L. H. Jones, Chem. Commun., 2009, 0, 547
    DOI: 10.1039/B817527F

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